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- W4252636179 abstract "Abstract Readily available alkenylphenols react with allenes under rhodium catalysis to provide valuable 2,2‐disubstituted 2H‐chromenes. The whole process, which involves the cleavage of one CH bond of the alkenyl moiety and the participation of the allene as a one‐carbon cycloaddition partner, can be considered a simple, versatile, and atom‐economical (5+1) heteroannulation. The reaction tolerates a broad range of substituents both in the alkenylphenol and in the allene, and most probably proceeds through a mechanism involving a rhodium‐catalyzed CC coupling followed by two sequential pericyclic processes." @default.
- W4252636179 created "2022-05-12" @default.
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- W4252636179 date "2015-01-07" @default.
- W4252636179 modified "2023-10-18" @default.
- W4252636179 title "Rhodium‐Catalyzed (5+1) Annulations Between 2‐Alkenylphenols and Allenes: A Practical Entry to 2,2‐Disubstituted 2<i>H</i>‐Chromenes" @default.
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- W4252636179 doi "https://doi.org/10.1002/ange.201410350" @default.
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