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- W4252857283 abstract "Abstract A novel heteroannulation reaction between α‐amino imides and in situ generated arynes has been developed for the synthesis of 2,2‐disubstituted indolin‐3‐ones. An enantioselective total synthesis of the marine alkaloid (+)‐hinckdentine A was subsequently accomplished using this reaction as a key step. A catalytic enantioselective Michael addition of an α‐aryl‐α‐isocyanoacetate to phenyl vinyl selenone was employed for the construction of the enantioenriched α‐quaternary α‐amino ester." @default.
- W4252857283 created "2022-05-12" @default.
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- W4252857283 date "2018-04-17" @default.
- W4252857283 modified "2023-10-02" @default.
- W4252857283 title "Heteroannulation of Arynes with α-Amino Imides: Synthesis of 2,2-Disubstituted Indolin-3-ones and Application to the Enantioselective Total Synthesis of (+)-Hinckdentine A" @default.
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- W4252857283 doi "https://doi.org/10.1002/ange.201800746" @default.
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