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- W4252932556 abstract "The effects of pressure and water on the adsorbed state of nitrogen dioxide on silver powder produced from an aqueous solution of AgNO 3 were studied by SERS. NO 2 of 10 2 Pa was added to the silver powder in the sample chamber and then pressure was raised up to ∼ 10 5 Pa with dry Ar, N 2 or O 2 . The observed surface species are NO - 3 and NO - 2 ions under atmospheric pressure. When the total pressure decreases, NO - 2 is transformed into NO - 3 and NO + . This reaction is reversible with the total pressure variation of dry gases regardless of kind. Once the silver powder adsorbing nitrogen oxides is exposed to moistened gas or air of ∼ 10 5 Pa, the reversible variation was interrupted, and NO - 3 and NO - 2 ions are observed on the silver surface." @default.
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- W4252932556 date "1986-07-01" @default.
- W4252932556 modified "2023-09-25" @default.
- W4252932556 title "SERS observation of the effects of pressure and water on the adsorbed state of nitrogen dioxide on a silver powder surface" @default.
- W4252932556 doi "https://doi.org/10.1016/0167-2584(86)90396-8" @default.
- W4252932556 hasPublicationYear "1986" @default.
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