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- W4253089314 abstract "Electro-reduction of titanic citrate in the pH range 2–10 indicates the existence of three different electroactive species depending on the pH. Around pH 2 and pH 8 species co-exist in equilibrium showing two cathodic waves. The electron transfer rate is slower on a glassy carbon electrode (GCE) when compared with Hg. The reduction wave for NH2OH on GCE is observed only in alkaline media and is controls the rate. In acid medium titanic citrate catalyses the reduction of NH2OH. In alkaline medium +NH3OH is more easily reducible and it is shown to catalyse the titanic citrate reduction. This is probably one of the first observations of catalyst-substrate interchangeability in redox catalysis. Quantitative evaluation of both catalytic processes indicates that the rate of the catalytic reaction depends on the formation of a complex between the reduced form of the catalyst and the substrate species." @default.
- W4253089314 created "2022-05-12" @default.
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- W4253089314 date "1985-08-23" @default.
- W4253089314 modified "2023-09-27" @default.
- W4253089314 title "Electron transfer and homogeneous redox catalysis on glassy carbon electrodes Part II. Redox catalysis showing catalyst-substrate interchangeability depending upon pH. The Ti(IV) citrate/NH2OH system in citric acid + trisodium citrate media" @default.
- W4253089314 doi "https://doi.org/10.1016/0368-1874(85)80097-6" @default.
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