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- W4253131859 abstract "Abstract Serendipitously, mono‐allyloxylated cucurbit[7]uril (AO 1 CB[7]) was discovered to act as an unconventional amphiphile which self‐assembles into light‐responsive vesicles (AO 1 CB[7]VC) in water. Although the mono‐allyloxy group, directly tethered on the periphery of CB[7], is much shorter (C4) than the hydrophobic tails of conventional amphiphiles, it played an important role in vesicle formation. Light‐activated transformation of the allyloxy group by conjugation with glutathione was exploited as a remote tool to disrupt the vesicle. The vesicle showed on‐demand release of cargo upon irradiation by a laser, after they were internalized into cancer cells. This result demonstrated the potential of AO 1 CB[7]VC as a new type of light‐responsive intracellular delivery vehicle for the release of therapeutic cargo, within cells, on demand." @default.
- W4253131859 created "2022-05-12" @default.
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- W4253131859 date "2018-02-21" @default.
- W4253131859 modified "2023-10-09" @default.
- W4253131859 title "Mono-allyloxylated Cucurbit[7]uril Acts as an Unconventional Amphiphile To Form Light-Responsive Vesicles" @default.
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- W4253131859 doi "https://doi.org/10.1002/ange.201713059" @default.
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