Matches in SemOpenAlex for { <https://semopenalex.org/work/W4253291214> ?p ?o ?g. }
- W4253291214 endingPage "25956" @default.
- W4253291214 startingPage "25950" @default.
- W4253291214 abstract "Abstract We report the palladium‐catalyzed gem ‐difluoroallylation of aryl halides and pseudo halides with 3,3‐difluoroallyl boronates in high yield with high regioselectivity, and we report the preparation of the 3,3‐difluoroallyl boronate reactants by a copper‐catalyzed defluorinative borylation of inexpensive gaseous 3,3,3‐trifluoropropene with bis(pinacolato)diboron. The gem ‐difluoroallylation of aryl and heteroaryl bromides proceeds with low catalyst loading (0.1 mol % [Pd]) and tolerates a wide range of functional groups, including primary alcohols, secondary amines, ethers, ketones, esters, amides, aldehydes, nitriles, halides, and nitro groups. This protocol extends to aryl iodides, chlorides, and triflates, as well as substituted difluoroallyl boronates, providing a versatile synthesis of gem ‐difluoroallyl arenes that we show to be valuable intermediates to a series of fluorinated building blocks." @default.
- W4253291214 created "2022-05-12" @default.
- W4253291214 creator A5003874093 @default.
- W4253291214 creator A5017036231 @default.
- W4253291214 creator A5063846270 @default.
- W4253291214 creator A5088865204 @default.
- W4253291214 date "2021-10-26" @default.
- W4253291214 modified "2023-10-11" @default.
- W4253291214 title "<i>gem</i> ‐Difluoroallylation of Aryl Halides and Pseudo Halides with Difluoroallylboron Reagents in High Regioselectivity" @default.
- W4253291214 cites W1978245422 @default.
- W4253291214 cites W2012404887 @default.
- W4253291214 cites W2056522781 @default.
- W4253291214 cites W2058570410 @default.
- W4253291214 cites W2072982389 @default.
- W4253291214 cites W2074683941 @default.
- W4253291214 cites W2084649736 @default.
- W4253291214 cites W2104605582 @default.
- W4253291214 cites W2121835375 @default.
- W4253291214 cites W2140841546 @default.
- W4253291214 cites W2144869962 @default.
- W4253291214 cites W2264719596 @default.
- W4253291214 cites W2316601347 @default.
- W4253291214 cites W2318890568 @default.
- W4253291214 cites W2321022167 @default.
- W4253291214 cites W2333129245 @default.
- W4253291214 cites W2334452370 @default.
- W4253291214 cites W2583745752 @default.
- W4253291214 cites W2593548406 @default.
- W4253291214 cites W2785609333 @default.
- W4253291214 cites W2800774792 @default.
- W4253291214 cites W2811461730 @default.
- W4253291214 cites W2884349368 @default.
- W4253291214 cites W2885058975 @default.
- W4253291214 cites W2888745810 @default.
- W4253291214 cites W2900093015 @default.
- W4253291214 cites W2902602253 @default.
- W4253291214 cites W2913227679 @default.
- W4253291214 cites W2914850818 @default.
- W4253291214 cites W2946457584 @default.
- W4253291214 cites W2950095321 @default.
- W4253291214 cites W2951882335 @default.
- W4253291214 cites W2952846256 @default.
- W4253291214 cites W2952917342 @default.
- W4253291214 cites W2965256032 @default.
- W4253291214 cites W2993073272 @default.
- W4253291214 cites W3017065016 @default.
- W4253291214 cites W3029810924 @default.
- W4253291214 cites W3080638221 @default.
- W4253291214 cites W4232039627 @default.
- W4253291214 cites W4235530979 @default.
- W4253291214 cites W4236729606 @default.
- W4253291214 cites W4243820610 @default.
- W4253291214 cites W4251701364 @default.
- W4253291214 cites W862097791 @default.
- W4253291214 doi "https://doi.org/10.1002/ange.202111476" @default.
- W4253291214 hasPublicationYear "2021" @default.
- W4253291214 type Work @default.
- W4253291214 citedByCount "4" @default.
- W4253291214 countsByYear W42532912142022 @default.
- W4253291214 countsByYear W42532912142023 @default.
- W4253291214 crossrefType "journal-article" @default.
- W4253291214 hasAuthorship W4253291214A5003874093 @default.
- W4253291214 hasAuthorship W4253291214A5017036231 @default.
- W4253291214 hasAuthorship W4253291214A5063846270 @default.
- W4253291214 hasAuthorship W4253291214A5088865204 @default.
- W4253291214 hasConcept C134121241 @default.
- W4253291214 hasConcept C155647269 @default.
- W4253291214 hasConcept C161790260 @default.
- W4253291214 hasConcept C171560689 @default.
- W4253291214 hasConcept C178790620 @default.
- W4253291214 hasConcept C185592680 @default.
- W4253291214 hasConcept C191897082 @default.
- W4253291214 hasConcept C192562407 @default.
- W4253291214 hasConcept C21951064 @default.
- W4253291214 hasConcept C2776413204 @default.
- W4253291214 hasConcept C2780263894 @default.
- W4253291214 hasConcept C2781076698 @default.
- W4253291214 hasConcept C40875361 @default.
- W4253291214 hasConcept C502130503 @default.
- W4253291214 hasConcept C59759590 @default.
- W4253291214 hasConceptScore W4253291214C134121241 @default.
- W4253291214 hasConceptScore W4253291214C155647269 @default.
- W4253291214 hasConceptScore W4253291214C161790260 @default.
- W4253291214 hasConceptScore W4253291214C171560689 @default.
- W4253291214 hasConceptScore W4253291214C178790620 @default.
- W4253291214 hasConceptScore W4253291214C185592680 @default.
- W4253291214 hasConceptScore W4253291214C191897082 @default.
- W4253291214 hasConceptScore W4253291214C192562407 @default.
- W4253291214 hasConceptScore W4253291214C21951064 @default.
- W4253291214 hasConceptScore W4253291214C2776413204 @default.
- W4253291214 hasConceptScore W4253291214C2780263894 @default.
- W4253291214 hasConceptScore W4253291214C2781076698 @default.
- W4253291214 hasConceptScore W4253291214C40875361 @default.
- W4253291214 hasConceptScore W4253291214C502130503 @default.
- W4253291214 hasConceptScore W4253291214C59759590 @default.
- W4253291214 hasFunder F4320335353 @default.
- W4253291214 hasIssue "49" @default.
- W4253291214 hasLocation W42532912141 @default.