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- W4253317546 abstract "1,2-Dihydro-1,3,2-diazaphosphinine 2 reacts with acetylene-dicarboxylic acid esters to give chemoselectively the adducts 5 or 6a, b, depending on the reaction conditions. Compound 6a is alternatively synthesized by treatment of equimolecular amounts of the previously described monoadduct 3(3′) and dimethyl acetylenedicarboxylate. A reaction pathway is proposed based primarily on i) the isolation and characterization of intermediate 8(8′) and ii) the reactivity of 3(3′) towards electrophiles, in particular with tetracyanoethylene (compound 10)." @default.
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- W4253317546 date "1998-07-01" @default.
- W4253317546 modified "2023-10-17" @default.
- W4253317546 title "Reaction of Dihydrodiazaphosphinines with Acetylenic Diesters: A Direct Synthesis of the λ5-Diazaphosphaazulene Skeleton" @default.
- W4253317546 doi "https://doi.org/10.1002/(sici)1099-0690(199807)1998:7<1425::aid-ejoc1425>3.3.co;2-s" @default.
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