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• W4253399380 abstract "Terminal arylalumylene complexes of platinum [Ar-Al-Pt(PCy3)2] (Ar=2,6-[CH(SiMe3)2]2C6H3 (Bbp) or 2,6-[CH(SiMe3)2]2-4-(tBu)C6H2 (Tbb)) have been synthesized either by the reaction of a dialumene–benzene adduct with [Pt(PCy3)2], or by the reduction of 1,2-dibromodialumanes Ar(Br)Al-Al(Br)Ar in the presence of [Pt(PCy3)2]. X-Ray crystallographic analysis reveals that the AlPt bond lengths of these arylalumylene complexes are shorter than the previously reported shortest AlPt distance. DFT calculations suggest that the AlPt bonds in the arylalumylene complexes have a significantly high electrostatic character." @default.
• W4253399380 created "2022-05-12" @default.
• W4253399380 creator A5004101977 @default.
• W4253399380 creator A5084824768 @default.
• W4253399380 creator A5089902442 @default.
• W4253399380 date "2014-03-11" @default.
• W4253399380 modified "2023-10-12" @default.
• W4253399380 title "Syntheses and Structures of Terminal Arylalumylene Complexes" @default.
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• W4253399380 doi "https://doi.org/10.1002/ange.201310559" @default.
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