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- W4253442842 abstract "A comparison between digital simulation and experimental ac and dc cyclic voltammetry of Mn(II) at mercury was used to elucidate its kinetics. Results indicated that below the saturation level a simple quasi-reversible charge-transfer mechanism is involved, with α=0.9. The consequences of this extreme charge-transfer asymmetry on anodic stripping voltammetry were considered, and slow scan rate experiments were found to enable satisfactory determination of Mn(II) to be carried out at very low concentrations. Linear calibration curves of current vs. concentration were obtained for both the hanging mercury drop and mercury thin film electrodes." @default.
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- W4253442842 date "1981-08-25" @default.
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- W4253442842 title "Ac and dc cyclic voltammetry of Mn(II) at mercury with applications to anodic stripping analysis" @default.
- W4253442842 doi "https://doi.org/10.1016/0368-1874(81)87166-3" @default.
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