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- W4253567503 abstract "Ein allgemeiner Ansatz zur Synthese von Hexahydrodibenzopyranen (HHDBPs) wird mit der enantioselektiven Totalsynthese von (+)-Machaeriol D illustriert. Schlüsselschritt ist der hoch regio- und stereoselektive Aufbau der vier Stereozentren des Naturstoffs in der SN2′-Reaktion eines Arylcyanocuprats mit dem Silylenolether eines optisch aktiven α,β-Epoxycyclohexanons (siehe Schema; R=Methoxymethyl; TMS=Trimethylsilyl, TBS=tert-Butyldimethylsilyl)." @default.
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- W4253567503 date "2006-05-18" @default.
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- W4253567503 title "Total Synthesis of (+)-Machaeriol D with a Key Regio- and Stereoselective SN2′ Reaction" @default.
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- W4253567503 doi "https://doi.org/10.1002/ange.200600006" @default.
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