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- W4253583845 abstract "A Cu-catalyzed carbonylative borylation of unactivated alkyl halides has been developed, enabling efficient synthesis of aliphatic potassium acyltrifluoroborates (KATs) in high yields by treating the in-situ formed tetracoordinated acylboron intermediates with aqueous KHF2. A variety of functional groups are tolerated under the mild reaction conditions, and primary, secondary and tertiary alkyl halides are all applicable. In addition, this method also provides facile access to N-methyliminodiacetyl (MIDA) acylboronates as well as α-methylated potassium acyltrifluoroborates in a one-pot manner. Mechanistic studies indicate a radical atom transfer carbonylation (ATC) mechanism to form acyl halide intermediates that are subsequently borylated by (NHC)CuBpin.<br>" @default.
- W4253583845 created "2022-05-12" @default.
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- W4253583845 date "2020-08-18" @default.
- W4253583845 modified "2023-10-16" @default.
- W4253583845 title "One-Step Synthesis of Acylboron Compounds via Cu-Catalyzed Carbonylative Borylation of Alkyl Halides" @default.
- W4253583845 doi "https://doi.org/10.26434/chemrxiv.12818180" @default.
- W4253583845 hasPublicationYear "2020" @default.
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