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- W4253626686 abstract "Abstract Electrical properties of self‐assembling DNA nanostructures underlie the paradigm of nanoscale bioelectronics, and as such require clear understanding. DNA‐mediated electron transfer (ET) from a gold electrode to DNA‐bound Methylene Blue (MB) shows directional preference, and it is sequence‐specific. During the electrocatalytic reduction of [Fe(CN) 6 ] 3− catalyzed by DNA‐bound MB, the ET rate constant for DNA‐mediated reduction of MB reaches (1.32±0.2)10 3 and (7.09±0.4)10 3 s −1 for (dGdC) 20 and (dAdT) 25 duplexes. The backward oxidation process is less efficient, making the DNA duplex a molecular rectifier. Lower rates of ET via (dGdC) 20 agree well with its disturbed π‐stacked sub‐molecular structure. Such direction‐ and sequence‐specific ET may be implicated in DNA oxidative damage and repair, and be relevant to other polarized surfaces, such as cell membranes and biomolecular interfaces." @default.
- W4253626686 created "2022-05-12" @default.
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- W4253626686 date "2018-12-05" @default.
- W4253626686 modified "2023-10-14" @default.
- W4253626686 title "Directional Preference of DNA‐Mediated Electron Transfer in Gold‐Tethered DNA Duplexes: Is DNA a Molecular Rectifier?" @default.
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- W4253626686 doi "https://doi.org/10.1002/ange.201809559" @default.
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