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- W4253711083 abstract "Studies of the electroreduction of cystine (RSSR) and oxidation of cysteine (RSH) at several pH's at a hanging Hg drop electrode by cyclic voltammetry and at a Hg pool by coulometry are described. The proposed mechanism for RSSR involves reduction of an adsorbed monolayer (maximum coverage of 41 μC cm−2) to form solution phase RSH at the adsorption prewave. A diffusion controlled reduction of RSSR to RSH occurs at more negative potentials. Oxidation of RSH involves formation of an adsorbed organomercury species, e.g., Hg(RS)2 (maximum coverage of 80 μC cm−2), which is reducible back to RSH. At higher RSH concentrations, anodic and cathodic current spikes appear on the cyclic voltammograms which are ascribed to formation of a tight or compact film when monolayer coverage of Hg(RS)2 is attained, corresponding to strong interactions between adsorbed species." @default.
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- W4253711083 date "1977-01-25" @default.
- W4253711083 modified "2023-10-18" @default.
- W4253711083 title "The electrochemistry of proteins and related substances I. Cystine and cysteine at the mercury electrode" @default.
- W4253711083 doi "https://doi.org/10.1016/s0368-1874(77)80038-5" @default.
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