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- W4253771356 abstract "Efficient and generic enantioselective discrimination of various chiral alcohols is achieved by using surface-enhanced Raman scattering (SERS) spectroscopy through charge–transfer (CT) contributions. The relative intensities of the peaks in the SERS spectra of a chiral selector are strongly dependent on the chirality of its surroundings. This highly distinct spectral discrepancy may be due to the tendency of chiral isomers to form intermolecular hydrogen-bonding complexes with the chiral selector in different molecular orientations, resulting in different CT states and SERS intensities of the adsorbates in the system. This study opens a new avenue leading to the development of novel enantiosensing strategies. A particular advantage of this approach is that it is label-free and does not employ any chiral reagents, including chiral light." @default.
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- W4253771356 date "2014-10-10" @default.
- W4253771356 modified "2023-09-26" @default.
- W4253771356 title "Enantioselective Discrimination of Alcohols by Hydrogen Bonding: A SERS Study" @default.
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- W4253771356 doi "https://doi.org/10.1002/ange.201407642" @default.
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