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- W4253834679 abstract "Abstract A novel method for the highly stereoselective synthesis of tetrahydropyrans is reported. This domino reaction is based on a twofold addition of enamides to aldehydes followed by a subsequent cyclization and furnishes fully substituted tetrahydropyrans in high yields. Three new σ‐bonds and five continuous stereogenic centers are formed in this one‐pot process with a remarkable degree of diastereoselectivity. In most cases, the formation of only one out of 16 possible diastereomers is observed. Two different stereoisomers can be accessed in a controlled fashion starting either from an E ‐ or a Z ‐configured enamide." @default.
- W4253834679 created "2022-05-12" @default.
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- W4253834679 date "2019-08-07" @default.
- W4253834679 modified "2023-10-12" @default.
- W4253834679 title "An Enamide‐Based Domino Reaction for a Highly Stereoselective Synthesis of Tetrahydropyrans" @default.
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- W4253834679 doi "https://doi.org/10.1002/ange.201907565" @default.
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