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- W4254083075 abstract "Abstract The 2,4–di–tert–butyl–6–methylphenyl substituent was placed on phosphorus of a phosphole, causing restricted rotation about the P–C bond and flattening of the phosphorus pyramid. Electron delocalization was greater in this phosphole as a result of the flattening. The 7–phosphanorbornene with this substituent had the most deshielded 31p nucleus ever recorded in this series, and thermally decomposed with formation of a diphosphene, suggesting a phosphinidene intermediate." @default.
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- W4254083075 date "1996-02-01" @default.
- W4254083075 modified "2023-09-25" @default.
- W4254083075 title "Effects of a Sterically Demanding P-Aryl Substituent in Phosphole and 7-Phosphanorbornene Chemistry" @default.
- W4254083075 doi "https://doi.org/10.1080/10426509608046291" @default.
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