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- W4254094489 abstract "The total vapour pressures of tellurium tetrachloride (TeCl4) and tetraiodide (TeI4) were measured by torsion-effusion method, and their temperature dependences are respectively represented by the following equations: log{p (kPa)} = (10.78 ± 0.20) − (5290 ± 100)/T (K); log{p (kPa) = (10.33 ± 0.40) − (4654 ± 150)/T (K). TeCl4 sublimes congruently, such that TeCl4(s) → TeCl4(g), and the standard sublimation enthalpy as obtained from second- and third-law treatments of the pressure data, and entropy associated with this reaction, are ΔsubHo(298) = 105 ± 2 kJ mol−1 and ΔsubSo(298) = 1804 ± 4 J K−1 mol−1. In the temperature range considered (340–396 K), TeI4(s) decomposes by the reaction and, in a minor amount, by the reaction The standard enthalpies and entropies of both reactions were calculated from the total vapour pressure data: ΔrHo(298) = 87 ± 4 kJ mol−1 and ΔrSo(298) = 163 ± 10 J K−1 mol−1 for the first reaction, and ΔrHo(298) = 181 ± 4 kJ mol−1 and ΔrSo(298) = 303 ± 12 J K−1 mol−1 for the second reaction. The heat of formation of TeI4(s), i.e.ΔforHo(298) = −50 ± 8 kJ mol−1, was also derived." @default.
- W4254094489 created "2022-05-12" @default.
- W4254094489 date "1965-06-01" @default.
- W4254094489 modified "2023-10-18" @default.
- W4254094489 title "536. Thermal desorption of Sr from W" @default.
- W4254094489 doi "https://doi.org/10.1016/0042-207x(65)90956-5" @default.
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