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- W4254112167 abstract "Das Knüpfen molekularer Knoten und ähnliche supramolekulare Synthesen lassen sich mit Metallkomplexen als Templaten leicht durchführen; die Kontrolle des stereochemischen Verlaufs solcher Reaktionen durch sterische Wechselwirkungen zwischen Metallbindungsstellen ist aber eine große Herausforderung. Eine einfache, gleichwohl allgemeine Kontrollmöglichkeit durch eine Klappbrücken-Strategie wird anhand der stereoselektiven Synthese eines dreikernigen Kupfer(I)-Bipyridin-Dreibeinkomplexes vorgestellt (siehe Bild)." @default.
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- W4254112167 date "2001-02-16" @default.
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- W4254112167 title "Trinuclear Copper(I)-bipyridine Triskelion: Template/Bascule Control of Coordination Complex Stereochemistry in a Trefoil Knot Precursor" @default.
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