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- W4254138735 abstract "The ability of bismuth to maneuver between different oxidation states in a catalytic redox cycle, mimicking the canonical organometallic steps associated to a transition metal, is an elusive and unprecedented approach in the field of homogeneous catalysis. Herein we present a catalytic protocol based on bismuth, a benign and sustainable main-group element, capable of performing every organometallic step in the context of oxidative fluorination of boron compounds; a territory reserved to transition metals. A rational ligand design featuring hypervalent coordination together with a mechanistic understanding of the fundamental steps, permitted a catalytic fluorination protocol based on a Bi(III)/Bi(V) redox couple, which represents a unique example where a main-group element is capable of outperforming its transition metal counterparts.<br>A main text and supplementary material have been attached as pdf files containing all the methodology, techniques and characterization of the compounds reported.<br>" @default.
- W4254138735 created "2022-05-12" @default.
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- W4254138735 date "2019-08-26" @default.
- W4254138735 modified "2023-09-23" @default.
- W4254138735 title "Catalytic Fluorination of Boron Compounds at a Bismuth Redox Platform" @default.
- W4254138735 doi "https://doi.org/10.26434/chemrxiv.9729143" @default.
- W4254138735 hasPublicationYear "2019" @default.
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