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- W4254174954 abstract "The mechanism of the electrohydrodimerization of an activated olefin, p-methylbenzylidene-malononitrile, is studied by convolution potential sweep voltammetry aiming at confirmation of the conclusion derived from the measurements of the peak potential shifts with sweep rate and initial concentration. It is shown that CPSV is a more powerful tool than LSV for discriminating between the numerous mechanistic possibilities, based on the fact that it uses more of the information available along the current potential curves. The various convoluted experimental current-potential curves which allows the possibilities to be reduced to only three cases. The final diagnosis is made on the basis of a study of the effect of water addition. It is confirmed that the coupling is of the radical-radical type and the rate constant is determined." @default.
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- W4254174954 date "1975-09-25" @default.
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- W4254174954 title "Electrodimerization XI. Coupling mechanism of an activated olefin: p-methylbenzylidene-malononitrile as studied by convolution potential sweep voltammetry" @default.
- W4254174954 doi "https://doi.org/10.1016/0368-1874(75)87013-4" @default.
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