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- W4254206660 abstract "Abstract This reaction is a general synthesis of pyrrole derivatives, especially penta‐substituted pyrroles, involving the 1,3‐dipolar cycloaddition of the mesoionic Δ 2 ‐oxazilium‐5‐olates to the corresponding acetylenic or olefinic dipolarophiles, followed by carbon dioxide evolution and subsequent aromatization or tautomerization and is generally referred to as the Huisgen pyrrole synthesis. The munchnones can be easily prepared by the acetic anhydride–induced dehydrative cyclization of N ‐alkyl‐ N ‐acyl‐α‐amino acids at high temperatures and the azomethine ylides can also be generated by the ring opening of aziridines. This reaction has been proved useful for the preparation of pyrrole derivatives." @default.
- W4254206660 created "2022-05-12" @default.
- W4254206660 date "2010-09-15" @default.
- W4254206660 modified "2023-10-03" @default.
- W4254206660 title "Huisgen Pyrrole Synthesis" @default.
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