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- W4254227923 abstract "[10545-99-0] Cl2S (MW 102.97) InChI = 1S/Cl2S/c1-3-2 InChIKey = FWMUJAIKEJWSSY-UHFFFAOYSA-N (electrophilic addition to alkenes and dienes;1 synthesis of heterocycles from eneimines and nitriles;2 and electrophile for the synthesis of sulfides3) Physical Data: mp −121 °C; bp 59 °C; d (20 °C) 1.621 g cm−3; n20D1.5570. Solubility: sol dichloromethane, n-hexane, CCl4, benzene; reacts violently with H2O, acetone, DMSO, DMF. Form Supplied in: dark-red liquid. Techgrade (80%), major impurity is S2Cl2. Also 1.0 M in CH2Cl2. Very pungent, chlorine-like odor. Readily decomposes to S2Cl2 and Cl2. Preparative Methods: can be synthesized from S(5) or S2Cl2.4 Purification: pure SCl2 can be obtained from Disulfur Dichloride and Chlorine by distillation from Phosphorus(III) Chloride. Handling, Storage, and Precautions: distilled SCl2 is stable for a few days in glass with a few drops of PCl3. Air and H2O sensitive. Incompatible with acids, bases, alcohols, plastics, amines. Avoid contact with metals. Corrosive; lachrymator. Harmful if swallowed, inhaled, or absorbed through the skin. Inhalation can be fatal. Possible carcinogen." @default.
- W4254227923 created "2022-05-12" @default.
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- W4254227923 date "2001-04-15" @default.
- W4254227923 modified "2023-09-24" @default.
- W4254227923 title "Sulfur Dichloride" @default.
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- W4254227923 doi "https://doi.org/10.1002/047084289x.rs133" @default.
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