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- W4254322647 abstract "Pentafluorophenylxenon(II) hexafluoroarsenate [C 6 F 5 Xe] + [AsF 6 ] − reacts in MeCN at 20 °C with aromatic compounds C 6 H 5 X ( X =CH 3 , F, CF 3 , NO 2 and CN) yielding isomeric mixtures of polyfluorinated biphenyls C 6 F 5 C 6 H 4 X . When X =I, iodopentafluorobenzene is formed in addition, whereas trimethylsilylbenzene ( X =SiMe 3 ) yields only C 6 F 5 C 6 H 5 and C 6 F 5 H. These results are compared with data of radical pentafluorophenylations and fluorination reactions with XeF 2 of the corresponding aromatic compounds. Polyfluoroaromatic compounds C 6 F 6 , C 6 F 5 H, C 6 F 5 I, C 6 F 5 CN and C 6 F 5 SiMe 3 do not react with [C 6 F 5 Xe] + [AsF 6 ] − under the same conditions." @default.
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- W4254322647 date "1992-08-01" @default.
- W4254322647 modified "2023-10-18" @default.
- W4254322647 title "Reactions of pentafluorophenylxenon(II) hexafluoroarsenate [C6F5Xe]+[AsF6]− with aromatic compounds" @default.
- W4254322647 doi "https://doi.org/10.1016/s0022-1139(00)80781-2" @default.
- W4254322647 hasPublicationYear "1992" @default.
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