Matches in SemOpenAlex for { <https://semopenalex.org/work/W4254322906> ?p ?o ?g. }
Showing items 1 to 71 of
71
with 100 items per page.
- W4254322906 abstract "Biogas, regarded as a promising renewable energy source, still needs to be upgraded. This calls for the removal of the most prominent contaminants, among others the octamethylcyclotetrasiloxane (D4) molecule. Herein, high throughput computational screening in tandem with synthesis and adsorption testing revealed the hydrophobic Zr-MOF PCN-777 as an optimal D4 adsorbent with record gravimetric (1.8 g/g) and volumetric (0.49 g/cm3) uptakes, alongside with a reversible and fast adsorption/desorption process, good cyclability and easy regeneration. This MOF was demonstrated to encompass an ideal combination of mesoporous cages and chemical functionality to enable an optimal packing of the siloxane molecules and their efficient removal while maintaining the process highly reversible thanks to moderately high host/guest interactions. This work highlights the efficacy of an integrated workflow for accelerating adsorbent selection for a desired application, spanning the entire pipeline from method validation to computational screening, synthesis and adsorption testing towards the identification of the optimal adsorbents.<br>" @default.
- W4254322906 created "2022-05-12" @default.
- W4254322906 creator A5003717704 @default.
- W4254322906 creator A5017075144 @default.
- W4254322906 creator A5025843095 @default.
- W4254322906 creator A5030121760 @default.
- W4254322906 creator A5079890502 @default.
- W4254322906 creator A5087859676 @default.
- W4254322906 creator A5088031513 @default.
- W4254322906 date "2021-03-19" @default.
- W4254322906 modified "2023-09-25" @default.
- W4254322906 title "Breaking the Upper Bound of Siloxane Uptake: Metal-Organic Frameworks as an Adsorbent Platform" @default.
- W4254322906 doi "https://doi.org/10.26434/chemrxiv.14222261" @default.
- W4254322906 hasPublicationYear "2021" @default.
- W4254322906 type Work @default.
- W4254322906 citedByCount "0" @default.
- W4254322906 crossrefType "posted-content" @default.
- W4254322906 hasAuthorship W4254322906A5003717704 @default.
- W4254322906 hasAuthorship W4254322906A5017075144 @default.
- W4254322906 hasAuthorship W4254322906A5025843095 @default.
- W4254322906 hasAuthorship W4254322906A5030121760 @default.
- W4254322906 hasAuthorship W4254322906A5079890502 @default.
- W4254322906 hasAuthorship W4254322906A5087859676 @default.
- W4254322906 hasAuthorship W4254322906A5088031513 @default.
- W4254322906 hasBestOaLocation W42543229061 @default.
- W4254322906 hasConcept C127413603 @default.
- W4254322906 hasConcept C150394285 @default.
- W4254322906 hasConcept C161790260 @default.
- W4254322906 hasConcept C162711632 @default.
- W4254322906 hasConcept C171250308 @default.
- W4254322906 hasConcept C178790620 @default.
- W4254322906 hasConcept C185592680 @default.
- W4254322906 hasConcept C192562407 @default.
- W4254322906 hasConcept C21880701 @default.
- W4254322906 hasConcept C2776139660 @default.
- W4254322906 hasConcept C2777118750 @default.
- W4254322906 hasConcept C41008148 @default.
- W4254322906 hasConcept C42360764 @default.
- W4254322906 hasConcept C521977710 @default.
- W4254322906 hasConcept C82776694 @default.
- W4254322906 hasConceptScore W4254322906C127413603 @default.
- W4254322906 hasConceptScore W4254322906C150394285 @default.
- W4254322906 hasConceptScore W4254322906C161790260 @default.
- W4254322906 hasConceptScore W4254322906C162711632 @default.
- W4254322906 hasConceptScore W4254322906C171250308 @default.
- W4254322906 hasConceptScore W4254322906C178790620 @default.
- W4254322906 hasConceptScore W4254322906C185592680 @default.
- W4254322906 hasConceptScore W4254322906C192562407 @default.
- W4254322906 hasConceptScore W4254322906C21880701 @default.
- W4254322906 hasConceptScore W4254322906C2776139660 @default.
- W4254322906 hasConceptScore W4254322906C2777118750 @default.
- W4254322906 hasConceptScore W4254322906C41008148 @default.
- W4254322906 hasConceptScore W4254322906C42360764 @default.
- W4254322906 hasConceptScore W4254322906C521977710 @default.
- W4254322906 hasConceptScore W4254322906C82776694 @default.
- W4254322906 hasLocation W42543229061 @default.
- W4254322906 hasOpenAccess W4254322906 @default.
- W4254322906 hasPrimaryLocation W42543229061 @default.
- W4254322906 hasRelatedWork W2037612017 @default.
- W4254322906 hasRelatedWork W2075573011 @default.
- W4254322906 hasRelatedWork W2118831863 @default.
- W4254322906 hasRelatedWork W2517962468 @default.
- W4254322906 hasRelatedWork W2748952813 @default.
- W4254322906 hasRelatedWork W2899084033 @default.
- W4254322906 hasRelatedWork W3014916856 @default.
- W4254322906 hasRelatedWork W3125207901 @default.
- W4254322906 hasRelatedWork W4224436599 @default.
- W4254322906 hasRelatedWork W4281682072 @default.
- W4254322906 isParatext "false" @default.
- W4254322906 isRetracted "false" @default.
- W4254322906 workType "article" @default.