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- W4254588063 abstract "Goldenes Händchen: Durch Gold-katalysierte intramolekulare Redoxreaktionen von Sulfinylalkinen werden α-Oxo-Au-Carbenoide erhalten. Diese können – neben ihrer Cyclisierung zu kondensierten Ringsystemen – an aufeinanderfolgenden Pinakol-Umlagerungen teilnehmen, die zu einer zweistufigen Insertion einer latenten Vinylcarbonylmethylengruppe in einen Aldehyd oder ein Keton führen (siehe Schema für die zweite Stufe)." @default.
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- W4254588063 date "2007-07-02" @default.
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- W4254588063 title "Gold-Catalyzed Intramolecular Redox Reaction of Sulfinyl Alkynes: Efficient Generation of α-Oxo Gold Carbenoids and Application in Insertion into RCO Bonds" @default.
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- W4254588063 doi "https://doi.org/10.1002/ange.200701449" @default.
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