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- W4254754613 abstract "Niobium chloride was studied with extended X-ray absorption fine structure spectroscopy (EXAFS) in acidic and basic aluminum chloride/1-ethyl-3-methyl imidazolium chloride (EMIC) ionic liquids. Although anhydrous Nb2Cl10 is more soluble in the basic melt than in the acidic melt, the EXAFS data shows that the coordination shell around the niobium does not change in the different ionic liquids. Both the acidic and basic melts show a coordination of five chlorides in the first shell. This indicates that in this series of ionic liquids, the Nb2Cl10 breaks up into two NbCl5 entities in both the acidic and the basic melts." @default.
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- W4254754613 date "2019-12-18" @default.
- W4254754613 modified "2023-10-18" @default.
- W4254754613 title "An XAFS Study of Niobium Chloride in the Ionic Liquid 1-Ethyl-3-Methyl Imidazolium Chloride/Aluminum Chloride" @default.
- W4254754613 doi "https://doi.org/10.1149/1.3159307" @default.
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