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- W4254839671 abstract "Expressions are derived for the small signal source impedance and the associated mean square noise voltage in the case of an irreversible redox reaction suitable for use when noise signals are studied by a novel cross-modulation method involving modulation of the electrochemical noise by an applied modulating signal. The analysis is based on the large signal aperiodic circuit for the faradaic reaction, the elementary sources of noise being evaluated by the application of the Nyquist, equation to diffusion resistance and a new equation, the semi-Nyquist equation, to resistance connected with unidirectional charge transfer processes. It is shown that the noise component of the current for a totally diffusion-controlled process is that predicted by the Schottky equation in agreement with results reported by Tyagai [2] and Levich [13]. The new most general form of the aperiodic circuit for a simple redox reaction contains a transformer, diodes and current sources in addition to the more usual speriodic circuit components but can be simplified somewhat with the aid of transitors." @default.
- W4254839671 created "2022-05-12" @default.
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- W4254839671 date "1977-09-09" @default.
- W4254839671 modified "2023-10-11" @default.
- W4254839671 title "Faradaic reaction noise" @default.
- W4254839671 doi "https://doi.org/10.1016/0368-1874(77)80331-6" @default.
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