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- W4255047072 abstract "In this article the X-ray investigation of tetramethylorthothiocarbonate C(SCH3)4 is described, a compound of particular interest with regard to its physical properties1). The modification stable below 23.2°C proved to be tetragonal, space group P421c (D2d4) Z = 2, a = 8.536 Å, c = 6.949 Å. A Bragg synthesis showed that the molecule C(SCH3)4 is built tetrahedrally with C - S = 1.81 Å. The structure can be simply described as a packing of methyl groups (r = 2 Å) arranged in a pattern resembling a body-centred lattice, the interstices of which are alternately empty, or filled with a CS4 group." @default.
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- W4255047072 date "1943-01-01" @default.
- W4255047072 modified "2023-09-25" @default.
- W4255047072 title "Order-disorder transformations in the lattice of organic molecules. II. The crystal structure of C(SCH3 )4 below 23.2°C" @default.
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- W4255047072 doi "https://doi.org/10.1002/recl.19430621008" @default.
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