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• W4255163917 endingPage "316" @default.
• W4255163917 startingPage "303" @default.
• W4255163917 abstract "The geometrical arrangement of sites favourable for formic acid oxidation and the poison formation reaction is determined using low index platinum single crystal planes. For this determination, the least number of sites required for the reactions to occur, which was obtained in the study of electrocatalysis by adatoms, was used, that is three adjacent sites are required for formic acid oxidation and four adjacent sites are required for poison formation. The triplet of sites on a unit lattice of Pt (111) and that on a unit lattice of Pt (100) plane are equally very favourable for the main oxidation reaction, but that on a unit lattice of Pt (110) is not so favourable as those on the former two planes. The oxidation rate is more than one order of magnitude lower on the latter than on the former triplets. The poison formation reaction proceeds at a very high rate on the (100) and the (110) planes. The geometrical arrangement of four sites on a square unit lattice of the (100) plane and on a rectangular unit lattice of the (110) plane are favourable for the poison formation reaction, but that on a hexagonal unit lattice of the (111) plane is not so favourable as the former two." @default.
• W4255163917 created "2022-05-12" @default.
• W4255163917 creator A5066780263 @default.
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• W4255163917 date "1985-03-01" @default.
• W4255163917 modified "2023-09-27" @default.
• W4255163917 title "Electrochemistry of platinum single crystal surfaces" @default.
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• W4255163917 doi "https://doi.org/10.1016/0368-1874(85)85535-0" @default.
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