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- W4255232708 abstract "[5813-48-9] CH3ClS (MW 82.56) InChI = 1S/CH3ClS/c1-3-2/h1H3 InChIKey = DDCYYCUMAFYDDU-UHFFFAOYSA-N (reacts as a pseudohalogen;1 reacts with carbanions and enolates to add the thiomethyl group α to the carbonyl;2, 3 adds across the double bonds of alkenes and allenes;4, 5 adds across triple bond of alkynes6, 7) Physical Data: bp 27–28 °C/53–60 mmHg. Solubility: sol ether, THF, dichloromethane, chloroform, carbon tetrachloride, dimethoxyethane. Preparative Method: by treatment of Dimethyl Disulfide at −15 °C with Sulfuryl Chloride, or by treatment of Methanethiol with Chlorine gas in CCl4 at −15 °C.1 The latter procedure may be considered a variation of the former since it involves the intermediate formation of the disulfide. The reagent is not commercially available. Purification: can be used crude from the above preparations. If purification is necessary it must be distilled at low temperature, under vacuum, due to its instability. Handling, Storage, and Precautions: undergoes decomposition within 1–2 d even when kept in a refrigerator; lasts less than 1 month when stored at −78 °C." @default.
- W4255232708 created "2022-05-12" @default.
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- W4255232708 date "2001-04-15" @default.
- W4255232708 modified "2023-09-24" @default.
- W4255232708 title "Methanesulfenyl Chloride" @default.
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- W4255232708 doi "https://doi.org/10.1002/047084289x.rm066" @default.
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