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- W4255280656 abstract "L-Phosphinothricin (6), a natural occurring amino acid which possesses herbicidal and antibiotical properties by inhibiting the enzyme glutamine synthetase (E.C. 6.3.1.2) in plants and bacteria, can be obtained with 99.4% enantiomeric excess via regioselective addition of alkyl methylphosphinates 4 to protected L-vinylglycine derivatives 3 followed by hydrolysis of the intermediates 5. L-Vinylglycine derivatives 3 are easily prepared from L-methionine (1a) and L-glutamic acid (1b). Protected L-vinylglycine derivatives 3 can also be used as starting materials in the enantioselective synthesis of L-2-aminobutyric acids bearing a phosphonate or phosphine oxide moiety in 4-position." @default.
- W4255280656 created "2022-05-12" @default.
- W4255280656 date "1989-05-01" @default.
- W4255280656 modified "2023-10-17" @default.
- W4255280656 title "Embedding additives into plastics" @default.
- W4255280656 doi "https://doi.org/10.1016/0306-3747(89)90452-1" @default.
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