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- W4255351324 abstract "Abstract Oxido‐iron(IV) porphyrin π‐radical cation species are involved in a variety of heme‐containing enzymes and have characteristic oxidation states consisting of a high‐valent iron center and a π‐conjugated macrocyclic ligand. However, the short lifetime of the complex has hampered detailed reactivity studies. Reported herein is a remarkable increase in the lifetime (80 s at 10 °C) of Fe IV (TMP +. )(O)(Cl) ( 2 ; TMP=5,10,15,20‐tetramesitylporphyrin dianion), produced by the oxidation of Fe III (TMP)(Cl) ( 1 ) by ozone in α,α,α‐trifluorotoluene (TFT). The lifetime is 720 times longer compared to that of the currently most stable species reported to date. The increase in the lifetime improves the reaction efficiency of 2 toward inert alkane substrates, and allowed observation of the reaction of 2 with a primary C−H bond (BDE C‐H =ca. 100 kcal mol −1 ) directly. Activation parameters for cyclohexane hydroxylation were also obtained." @default.
- W4255351324 created "2022-05-12" @default.
- W4255351324 creator A5028713831 @default.
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- W4255351324 creator A5039985062 @default.
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- W4255351324 date "2019-07-03" @default.
- W4255351324 modified "2023-10-14" @default.
- W4255351324 title "Direct Observation of Primary C−H Bond Oxidation by an Oxido‐Iron(IV) Porphyrin π‐Radical Cation Complex in a Fluorinated Carbon Solvent" @default.
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- W4255351324 doi "https://doi.org/10.1002/ange.201901608" @default.
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