Matches in SemOpenAlex for { <https://semopenalex.org/work/W4255432855> ?p ?o ?g. }
Showing items 1 to 79 of
79
with 100 items per page.
- W4255432855 abstract "Visible-light-induced dearomatization reaction <i>via</i> energy transfer mechanism is an emerging strategy for the synthesis of highly strained polycyclic molecules. Transient, high-energy diradical species on excited states are typically involved in this type of reactions as key intermediates. Herein, we report the visible-light-induced divergent dearomatization of indole-tethered O-methyl oximes, in which the reactivity of the open-shelled singlet diradical intermediates towards competitive reaction pathways, namely [2+2] cycloaddition and 1,5-hydrogen atom transfer, can be well regulated. The mechanism has been well supported by a series of experimental and computational investigations. The dearomatization reactions allow the facile synthesis of structurally appealing indoline-fused azetidines and related polycyclic molecules with high efficiency and exclusive selectivity." @default.
- W4255432855 created "2022-05-12" @default.
- W4255432855 creator A5002318539 @default.
- W4255432855 creator A5019588728 @default.
- W4255432855 creator A5021956079 @default.
- W4255432855 creator A5064536916 @default.
- W4255432855 date "2020-07-08" @default.
- W4255432855 modified "2023-09-26" @default.
- W4255432855 title "Visible-Light-Induced Dearomatization via [2+2] Cycloaddition or 1,5-Hydrogen Atom Transfer: Regulating Reaction Pathways of Diradicals on Excited States" @default.
- W4255432855 doi "https://doi.org/10.26434/chemrxiv.12623504" @default.
- W4255432855 hasPublicationYear "2020" @default.
- W4255432855 type Work @default.
- W4255432855 citedByCount "0" @default.
- W4255432855 crossrefType "posted-content" @default.
- W4255432855 hasAuthorship W4255432855A5002318539 @default.
- W4255432855 hasAuthorship W4255432855A5019588728 @default.
- W4255432855 hasAuthorship W4255432855A5021956079 @default.
- W4255432855 hasAuthorship W4255432855A5064536916 @default.
- W4255432855 hasBestOaLocation W42554328551 @default.
- W4255432855 hasConcept C117633835 @default.
- W4255432855 hasConcept C121332964 @default.
- W4255432855 hasConcept C142724271 @default.
- W4255432855 hasConcept C161790260 @default.
- W4255432855 hasConcept C178790620 @default.
- W4255432855 hasConcept C181500209 @default.
- W4255432855 hasConcept C185544564 @default.
- W4255432855 hasConcept C185592680 @default.
- W4255432855 hasConcept C192527728 @default.
- W4255432855 hasConcept C192937433 @default.
- W4255432855 hasConcept C204787440 @default.
- W4255432855 hasConcept C21951064 @default.
- W4255432855 hasConcept C2776640939 @default.
- W4255432855 hasConcept C2776910235 @default.
- W4255432855 hasConcept C2779664164 @default.
- W4255432855 hasConcept C2779890007 @default.
- W4255432855 hasConcept C2780263894 @default.
- W4255432855 hasConcept C32909587 @default.
- W4255432855 hasConcept C33062035 @default.
- W4255432855 hasConcept C71240020 @default.
- W4255432855 hasConcept C71924100 @default.
- W4255432855 hasConcept C75473681 @default.
- W4255432855 hasConceptScore W4255432855C117633835 @default.
- W4255432855 hasConceptScore W4255432855C121332964 @default.
- W4255432855 hasConceptScore W4255432855C142724271 @default.
- W4255432855 hasConceptScore W4255432855C161790260 @default.
- W4255432855 hasConceptScore W4255432855C178790620 @default.
- W4255432855 hasConceptScore W4255432855C181500209 @default.
- W4255432855 hasConceptScore W4255432855C185544564 @default.
- W4255432855 hasConceptScore W4255432855C185592680 @default.
- W4255432855 hasConceptScore W4255432855C192527728 @default.
- W4255432855 hasConceptScore W4255432855C192937433 @default.
- W4255432855 hasConceptScore W4255432855C204787440 @default.
- W4255432855 hasConceptScore W4255432855C21951064 @default.
- W4255432855 hasConceptScore W4255432855C2776640939 @default.
- W4255432855 hasConceptScore W4255432855C2776910235 @default.
- W4255432855 hasConceptScore W4255432855C2779664164 @default.
- W4255432855 hasConceptScore W4255432855C2779890007 @default.
- W4255432855 hasConceptScore W4255432855C2780263894 @default.
- W4255432855 hasConceptScore W4255432855C32909587 @default.
- W4255432855 hasConceptScore W4255432855C33062035 @default.
- W4255432855 hasConceptScore W4255432855C71240020 @default.
- W4255432855 hasConceptScore W4255432855C71924100 @default.
- W4255432855 hasConceptScore W4255432855C75473681 @default.
- W4255432855 hasLocation W42554328551 @default.
- W4255432855 hasOpenAccess W4255432855 @default.
- W4255432855 hasPrimaryLocation W42554328551 @default.
- W4255432855 hasRelatedWork W10810920 @default.
- W4255432855 hasRelatedWork W12489224 @default.
- W4255432855 hasRelatedWork W12718986 @default.
- W4255432855 hasRelatedWork W16051966 @default.
- W4255432855 hasRelatedWork W19305012 @default.
- W4255432855 hasRelatedWork W23653077 @default.
- W4255432855 hasRelatedWork W24870503 @default.
- W4255432855 hasRelatedWork W25946987 @default.
- W4255432855 hasRelatedWork W6477459 @default.
- W4255432855 hasRelatedWork W7447090 @default.
- W4255432855 isParatext "false" @default.
- W4255432855 isRetracted "false" @default.
- W4255432855 workType "article" @default.