Matches in SemOpenAlex for { <https://semopenalex.org/work/W4255610706> ?p ?o ?g. }
Showing items 1 to 56 of
56
with 100 items per page.
- W4255610706 endingPage "4768" @default.
- W4255610706 startingPage "4765" @default.
- W4255610706 abstract "A new method to generate chiral cis-vinyloxiranes from readily available starting materials is reported. (α-Chloroallyl)lithium, generated in situ from LiN(c-Hex)2 and allyl chloride at −95°C, reacts with (−)-β-methoxydiisopinocampheylborane, dIpc2BOMe, to give an ate complex. Treatment of this with BF3·OEt2 leads to the reagent, [(Z)-γ-chloroallyl]BIpc2. Chloroallylboration of aldehydes using the latter reagent followed by elimination of chiral auxiliary provides syn-α-chlorohydrins in high de (≥94%) and ee (90–99%). Base-induced cyclization of chlorohydrins furnishes chiral cis-vinyloxiranes." @default.
- W4255610706 created "2022-05-12" @default.
- W4255610706 creator A5042692218 @default.
- W4255610706 date "1995-07-03" @default.
- W4255610706 modified "2023-10-18" @default.
- W4255610706 title "New Access to Chiral syn-α-Chlorohydrins and cis-Vinyloxiranes through Chloroallylboration" @default.
- W4255610706 doi "https://doi.org/10.1016/00404-0399(50)09286-" @default.
- W4255610706 hasPublicationYear "1995" @default.
- W4255610706 type Work @default.
- W4255610706 citedByCount "0" @default.
- W4255610706 crossrefType "journal-article" @default.
- W4255610706 hasAuthorship W4255610706A5042692218 @default.
- W4255610706 hasConcept C134018914 @default.
- W4255610706 hasConcept C134306372 @default.
- W4255610706 hasConcept C155647269 @default.
- W4255610706 hasConcept C178790620 @default.
- W4255610706 hasConcept C185592680 @default.
- W4255610706 hasConcept C21951064 @default.
- W4255610706 hasConcept C2778541603 @default.
- W4255610706 hasConcept C2778695967 @default.
- W4255610706 hasConcept C33923547 @default.
- W4255610706 hasConcept C40875361 @default.
- W4255610706 hasConcept C42058472 @default.
- W4255610706 hasConcept C71924100 @default.
- W4255610706 hasConceptScore W4255610706C134018914 @default.
- W4255610706 hasConceptScore W4255610706C134306372 @default.
- W4255610706 hasConceptScore W4255610706C155647269 @default.
- W4255610706 hasConceptScore W4255610706C178790620 @default.
- W4255610706 hasConceptScore W4255610706C185592680 @default.
- W4255610706 hasConceptScore W4255610706C21951064 @default.
- W4255610706 hasConceptScore W4255610706C2778541603 @default.
- W4255610706 hasConceptScore W4255610706C2778695967 @default.
- W4255610706 hasConceptScore W4255610706C33923547 @default.
- W4255610706 hasConceptScore W4255610706C40875361 @default.
- W4255610706 hasConceptScore W4255610706C42058472 @default.
- W4255610706 hasConceptScore W4255610706C71924100 @default.
- W4255610706 hasIssue "27" @default.
- W4255610706 hasLocation W42556107061 @default.
- W4255610706 hasOpenAccess W4255610706 @default.
- W4255610706 hasPrimaryLocation W42556107061 @default.
- W4255610706 hasRelatedWork W1997299886 @default.
- W4255610706 hasRelatedWork W2020458665 @default.
- W4255610706 hasRelatedWork W2058529431 @default.
- W4255610706 hasRelatedWork W2325092347 @default.
- W4255610706 hasRelatedWork W2341011754 @default.
- W4255610706 hasRelatedWork W2395630660 @default.
- W4255610706 hasRelatedWork W2951556410 @default.
- W4255610706 hasRelatedWork W2952439925 @default.
- W4255610706 hasRelatedWork W2952561289 @default.
- W4255610706 hasRelatedWork W2953155228 @default.
- W4255610706 hasVolume "36" @default.
- W4255610706 isParatext "false" @default.
- W4255610706 isRetracted "false" @default.
- W4255610706 workType "article" @default.