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- W4255628351 abstract "Abstract Proton reduction is one of the most fundamental and important reactions in nature. MoS 2 edges have been identified as the active sites for hydrogen evolution reaction (HER) electrocatalysis. Designing molecular mimics of MoS 2 edge sites is an attractive strategy to understand the underlying catalytic mechanism of different edge sites and improve their activities. Herein we report a dimeric molecular analogue [Mo 2 S 12 ] 2− , as the smallest unit possessing both the terminal and bridging disulfide ligands. Our electrochemical tests show that [Mo 2 S 12 ] 2− is a superior heterogeneous HER catalyst under acidic conditions. Computations suggest that the bridging disulfide ligand of [Mo 2 S 12 ] 2− exhibits a hydrogen adsorption free energy near zero (−0.05 eV). This work helps shed light on the rational design of HER catalysts and biomimetics of hydrogen‐evolving enzymes." @default.
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- W4255628351 date "2015-10-20" @default.
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- W4255628351 title "Dimeric [Mo <sub>2</sub> S <sub>12</sub> ] <sup>2−</sup> Cluster: A Molecular Analogue of MoS <sub>2</sub> Edges for Superior Hydrogen‐Evolution Electrocatalysis" @default.
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- W4255628351 doi "https://doi.org/10.1002/ange.201507529" @default.
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