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- W4255655206 abstract "Layers of Ag electrodeposited from aqueous solution onto a Pt(S)[6(111)×(111)](3×T)-I adlattice formed by pretreatment of the Pt(S)[6(111)×(111)] surface with I2 vapor were studied by LEED, AES and thermal desorption. Stability of the I adlattice toward exposure to perchloric acid solution, and persistence of I on the surface during multiple cycles of electrodeposition and dissolution of Ag was demonstrated. The I adlattice served to protect the Pt and Ag electrodeposited surfaces from unwanted side reactions. Electrodeposition of Ag occurred in three well-resolved UPD regions. Subsequent UHV experiments, after each UPD peak and up to coverages of a few monolayers, revealed that stable and ordered Ag superlattices were formed, each UPD region leading to a change in LEED pattern and superlattice structure. These results are compared with previous results for smooth Pt(111), revealing clues as to the role of steps in electrodeposition." @default.
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- W4255655206 date "1984-09-25" @default.
- W4255655206 modified "2023-09-26" @default.
- W4255655206 title "Studies of electrodeposition of silver on an iodine-pretreated stepped surface: Pt(S)[6(111)×(111)]" @default.
- W4255655206 doi "https://doi.org/10.1016/0368-1874(84)83479-6" @default.
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