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- W4255736186 endingPage "2548" @default.
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- W4255736186 abstract "Tetrahydropyrans are common motifs in natural products and have now been constructed with high stereocontrol through a three-component allylboration-Prins reaction sequence. This methodology has been applied to a concise (13 steps) and efficient (14 % overall yield) synthesis of the macrolide (−)-clavosolide A. The synthesis also features an early stage glycosidation reaction to introduce the xylose moiety and a lithiation-borylation reaction to attach the cyclopropyl-containing side chain." @default.
- W4255736186 created "2022-05-12" @default.
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- W4255736186 date "2016-01-14" @default.
- W4255736186 modified "2023-10-16" @default.
- W4255736186 title "Tandem Allylboration-Prins Reaction for the Rapid Construction of Substituted Tetrahydropyrans: Application to the Total Synthesis of (−)-Clavosolide A" @default.
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- W4255736186 doi "https://doi.org/10.1002/ange.201511140" @default.
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