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- W4255896787 abstract "Little is known about the hydrogenation of fused aromatic nuclei during the liquefaction of coal under the influence of Lewis acid catalysts. This study was conducted to establish the effects of catalyst acidity on the activity and selectivity of Lewis acid catalysts, the sources of hydrogen involved in hydrogenation and cracking, and the relations between reactant structure and reactivity. Two-ring aromatic and hydroaromatic compounds were used to simulate some of the structural units present in coal. The catalysts examined were ZnCl2 and AlCl3. ZnCl2 is less active than AlCl3 for both hydrogenation and cracking but it does not promote the formation of tars via Scholl condensation: Methyl or hydroxyl substitution of the reactants greatly enhances their reactivity towards hydrogenation and cracking. The source of hydrogen consumed during hydrogenation depends on the choice of catalyst. In the presence of AlCl3, Scholl condensation of aromatic nuclei serves as the principal source of hydrogen. Molecular hydrogen is used exclusively, though, when hydrogenation is catalysed by ZnCl2. The formation of reaction products and the trends in reactant reactivity can be interpreted on the basis of carbonium ion mechanisms. The results of this study provide a basis for assessing the extent of hydrogenation occurring during the liquefaction of coal using ZnCl2 or AlCl3." @default.
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- W4255896787 date "1982-08-01" @default.
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- W4255896787 title "Effects of Lewis acid catalysts on the hydrogenation and cracking of two-ring aromatic and hydroaromatic structures related to coal" @default.
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- W4255896787 doi "https://doi.org/10.1016/0016-2361(82)90251-4" @default.
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