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- W4255911245 abstract "Abstract The mechanistic uniqueness and versatility of borrowing hydrogen catalysis provides an opportunity to investigate the controllability of a cascade reaction, and more importantly, to realize either one or both of chiral recognition and chiral induction simultaneously. Here we report that, in a borrowing hydrogen cascade starting from racemic allylic alcohols, one of the enantiomers could be kinetically resolved, while the other enantiomer could be purposely converted to various targeted products, including α,β‐unsaturated ketones, β‐functionalized ketones and γ‐functionalized alcohols. By employing a robust Ru‐catalyst, both kinetic resolution and asymmetric induction were achieved with remarkable levels of efficiency and enantioselectivity. Density functional theory (DFT) calculations suggest that corresponding catalyst–substrate π–π interactions are pivotal to realize the observed stereochemical diversity." @default.
- W4255911245 created "2022-05-12" @default.
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- W4255911245 date "2021-11-16" @default.
- W4255911245 modified "2023-09-30" @default.
- W4255911245 title "Simultaneous Kinetic Resolution and Asymmetric Induction within a Borrowing Hydrogen Cascade Mediated by a Single Catalyst" @default.
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- W4255911245 doi "https://doi.org/10.1002/ange.202112993" @default.
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