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• W4256046927 endingPage "3771" @default.
• W4256046927 startingPage "3767" @default.
• W4256046927 abstract "The combination of aryl bromides, allylbenzene, base and a palladium catalyst usually results in a Heck reaction. Herein we combine these same reagents, but override the Heck pathway by employing a strong base. In the presence of LiN(SiMe3)2, allylbenzene derivatives undergo reversible deprotonation. Transmetalation of the resulting allyllithium intermediate to LPdAr(Br) and reductive elimination provide the 1,1-diarylprop-2-enes, which are not accessible by the Heck reaction. The regioselectivity in this deprotonative cross-coupling process is catalyst-controlled and very high." @default.
• W4256046927 created "2022-05-12" @default.
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• W4256046927 date "2014-02-26" @default.
• W4256046927 modified "2023-10-18" @default.
• W4256046927 title "Chemo- and Regioselective C(sp³)H Arylation of Unactivated Allylarenes by Deprotonative Cross-Coupling" @default.
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• W4256046927 doi "https://doi.org/10.1002/ange.201309084" @default.
• W4256046927 hasPublicationYear "2014" @default.
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