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- W4256075380 abstract "Abstract The control of inter‐lattice magnetic interactions is a crucial issue when long‐range ordered magnets that are based on low‐dimensional magnetic frameworks are designed. A “pillared layer framework (PLF)” model could be an efficient system for this purpose. In this report, A magnet based on a π‐stacked PLF with a phase transition temperature of 82 K, which can be increased to 107 K by applying a pressure of 12.5 kbar, is rationally constructed. Two types of low‐dimensional magnetic framework systems, an electron donor/acceptor magnetic layer and a charge transfer [FeCp* 2 ] + TCNQ .− columnar magnet ([FeCp* 2 ] + =decamethylferrocenium; TCNQ=7,7,8,8‐tetracyano‐ p ‐quinodimethane), are integrated to fabricate the magnet. This synthetic strategy employing a combination of layers and chains is widely useful not only for magnet design, but also for the creation of multifunctional materials with pores and anisotropic frameworks." @default.
- W4256075380 created "2022-05-12" @default.
- W4256075380 creator A5041013867 @default.
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- W4256075380 date "2014-11-24" @default.
- W4256075380 modified "2023-10-14" @default.
- W4256075380 title "Magnet Design by Integration of Layer and Chain Magnetic Systems in a π-Stacked Pillared Layer Framework" @default.
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- W4256075380 doi "https://doi.org/10.1002/ange.201410057" @default.
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