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- W4256122004 abstract "Abstract A new approach for the efficient synthesis of eight‐membered lactams through formal [6+2] cyclization of siloxy alkynes and vinylazetidines has been developed. Evidence from a chirality transfer experiment suggests that the reaction proceeds via a [3,3]‐sigmatropic rearrangement from a ketene intermediate. This insight led to the development of alternative conditions and use of acyl chlorides as ketene precursors for the [6+2] reaction with vinylazetidines." @default.
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- W4256122004 date "2019-04-09" @default.
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- W4256122004 title "Synthesis of Eight‐Membered Lactams through Formal [6+2] Cyclization of Siloxy Alkynes and Vinylazetidines" @default.
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- W4256122004 doi "https://doi.org/10.1002/ange.201902866" @default.
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