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- W4256125722 abstract "The positions of double bonds in lipids play critical roles in their biochemical and biophysical properties. In this study, by coupling Paternò–Büchi (P-B) reaction with tandem mass spectrometry, we developed a novel method that can achieve confident, fast, and sensitive determination of double bond locations within various types of lipids. The P-B reaction is facilitated by UV irradiation of a nanoelectrospray plume entraining lipids and acetone. Tandem mass spectrometry of the on-line reaction products via collision activation leads to the rupture of oxetane rings and the formation of diagnostic ions specific to the double bond location." @default.
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- W4256125722 date "2014-02-05" @default.
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- W4256125722 title "Pinpointing Double Bonds in Lipids by Paternò-Büchi Reactions and Mass Spectrometry" @default.
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- W4256125722 doi "https://doi.org/10.1002/ange.201310699" @default.
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