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- W4256129849 abstract "Abstract A ground‐state boron atom inserts into the C=C bond of ethylene to spontaneously form the allene‐like compound H 2 CBCH 2 on annealing in solid neon. This compound can further isomerize to the propyne‐like HCBCH 3 isomer under UV light excitation. The observation of this unique spontaneous C=C bond insertion reaction is consistent with theoretical predictions that the reaction is thermodynamically exothermic and kinetically facile. This work demonstrates that the stronger C=C bond, rather than the less inert C−H bond, can be broken to form organoboron species from the reaction of a boron atom with ethylene even at cryogenic temperatures." @default.
- W4256129849 created "2022-05-12" @default.
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- W4256129849 date "2016-05-30" @default.
- W4256129849 modified "2023-10-16" @default.
- W4256129849 title "Observation of Spontaneous C=C Bond Breaking in the Reaction between Atomic Boron and Ethylene in Solid Neon" @default.
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- W4256129849 doi "https://doi.org/10.1002/ange.201603345" @default.
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