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- W4256142725 abstract "[5796-98-5] C6H18O2Si2 (MW 178.38) InChI = 1S/C6H18O2Si2/c1-9(2,3)7-8-10(4,5)6/h1-6H3 InChIKey = XPEMYYBBHOILIJ-UHFFFAOYSA-N (a masked form of 100% hydrogen peroxide;2 synthon of HO+ for electrophilic hydroxylation;3, 4 source of Me3SiO+ for electrophilic oxidations;4-6 a versatile oxidant for alcohols, ketones, phosphines, phosphites, and sulfides1, 2, 7) Physical Data: bp 41 °C/30 mmHg;7 n20D 1.3970.1b Solubility: highly sol aprotic organic solvents. Form Supplied in: colorless oil; used as an anhydrous and protected form of hydrogen peroxide; 10% solution in hexane or in CH2Cl2. Analysis of Reagent Purity: 1H NMR (s) δ 0.18 ppm;3 29Si NMR δ 27.2 ppm.8 Preparative Methods: obtained in 80–96% yields by reaction of Chlorotrimethylsilane with 1,4‐Diazabicyclo[2.2.2]octane·(H2O2)2,3 Hexamethylenetetramine·H2O2,8 or Hydrogen Peroxide–Urea in CH2Cl2.9 Handling, Storage, and Precautions: thermally stable; can be handled in the pure state and distilled;8 rearranges at 150–180 °C.1c" @default.
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- W4256142725 date "2007-09-17" @default.
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- W4256142725 title "Bis(trimethylsilyl) Peroxide" @default.
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