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• W4256148101 abstract "Abstract Scanning tunnelling microscope observations at the 1‐phenyloctane/graphite interface reveal how chiral structural information at the molecular level is transferred and expressed structurally at the 2D supramolecular level for a porous system. The chirality of self‐assembled molecular networks formed by chiral dehydrobenzo[12]annulene (cDBA) derivatives having three chiral chains and three achiral chains, alternatingly, is compared with those of cDBAs having six chiral chains reported previously. While for all cDBAs homochiral surfaces are formed, their handedness is not simply a reflection of the absolute configuration of the stereogenic centres. Both the number of stereogenic centres as well as the length of the achiral chains determine the supramolecular handedness, providing a deep insight into the supramolecular chirality induction mechanisms at play. Moreover, these cDBAs act to induce chirality in porous networks formed by achiral DBAs." @default.
• W4256148101 created "2022-05-12" @default.
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• W4256148101 date "2019-05-02" @default.
• W4256148101 modified "2023-09-27" @default.
• W4256148101 title "Reversing the Handedness of Self‐Assembled Porous Molecular Networks through the Number of Identical Chiral Centres" @default.
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• W4256148101 doi "https://doi.org/10.1002/ange.201902565" @default.
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