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- W4256237257 abstract "Die 5-exo-dig-Carbocyclisierung von 1 zu 2 verläuft über eine intramolekulare Carbopalladierung der Alkinfunktion mit einem Pd-Enolat (siehe Schema). DFT-Rechnungen zufolge entsteht das Pd-Enolat durch eine PdII-acetat-vermittelte Deprotonierung. Anschließend führen die intramolekulare Carbopalladierung, eine Z-E-Isomerisierung der gebildeten Vinylpalladiumspezies und eine Protiodepalladierung zu den E-Alkylidenindanonen. Detailed facts of importance to specialist readers are published as ”Supporting Information”. Such documents are peer-reviewed, but not copy-edited or typeset. They are made available as submitted by the authors. Please note: The publisher is not responsible for the content or functionality of any supporting information supplied by the authors. Any queries (other than missing content) should be directed to the corresponding author for the article." @default.
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- W4256237257 date "2011-02-08" @default.
- W4256237257 modified "2023-10-17" @default.
- W4256237257 title "Palladium-Catalyzed Carbocyclization of Alkynyl Ketones Proceeding through a Carbopalladation Pathway" @default.
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- W4256237257 doi "https://doi.org/10.1002/ange.201006751" @default.
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