Matches in SemOpenAlex for { <https://semopenalex.org/work/W4256238377> ?p ?o ?g. }
Showing items 1 to 65 of
65
with 100 items per page.
- W4256238377 abstract "Absolute asymmetric synthesis produces chiral molecules without any chiral polarization and is an interesting rational for the origin of homochirality. Remarkably, in the Soai reaction absolute asymmetric amplification of alkanol product is observed under heterogenous conditions. Reaction of iPr2Zn vapor on solid carbaldehyde produced corresponding alkanol with up to 96% ee. In a parallel amplification process, a chiral ester is produced with 98% ee. The latter is attributed to disproportionation of starting aldehyde into hemiacetal followed by a subsequent Claisen-Tishchenko mechanism. This observation provide evidence for the debated transient intermediate, and opens new perspectives in the elucidation of the mechanism of amplification of chirality in the Soai reaction." @default.
- W4256238377 created "2022-05-12" @default.
- W4256238377 creator A5033042240 @default.
- W4256238377 creator A5040424506 @default.
- W4256238377 date "2021-08-02" @default.
- W4256238377 modified "2023-09-28" @default.
- W4256238377 title "Validation of a hemiacetal intermediate during absolute Soai autocatalytic amplification under heterogenous phase" @default.
- W4256238377 doi "https://doi.org/10.26434/chemrxiv-2021-ls95s" @default.
- W4256238377 hasPublicationYear "2021" @default.
- W4256238377 type Work @default.
- W4256238377 citedByCount "0" @default.
- W4256238377 crossrefType "posted-content" @default.
- W4256238377 hasAuthorship W4256238377A5033042240 @default.
- W4256238377 hasAuthorship W4256238377A5040424506 @default.
- W4256238377 hasBestOaLocation W42562383771 @default.
- W4256238377 hasConcept C121332964 @default.
- W4256238377 hasConcept C124668440 @default.
- W4256238377 hasConcept C146888428 @default.
- W4256238377 hasConcept C161790260 @default.
- W4256238377 hasConcept C17365422 @default.
- W4256238377 hasConcept C178790620 @default.
- W4256238377 hasConcept C185592680 @default.
- W4256238377 hasConcept C20621625 @default.
- W4256238377 hasConcept C25170562 @default.
- W4256238377 hasConcept C2776572972 @default.
- W4256238377 hasConcept C2778564446 @default.
- W4256238377 hasConcept C2779825165 @default.
- W4256238377 hasConcept C37263863 @default.
- W4256238377 hasConcept C486523 @default.
- W4256238377 hasConcept C62520636 @default.
- W4256238377 hasConcept C71240020 @default.
- W4256238377 hasConcept C7602139 @default.
- W4256238377 hasConceptScore W4256238377C121332964 @default.
- W4256238377 hasConceptScore W4256238377C124668440 @default.
- W4256238377 hasConceptScore W4256238377C146888428 @default.
- W4256238377 hasConceptScore W4256238377C161790260 @default.
- W4256238377 hasConceptScore W4256238377C17365422 @default.
- W4256238377 hasConceptScore W4256238377C178790620 @default.
- W4256238377 hasConceptScore W4256238377C185592680 @default.
- W4256238377 hasConceptScore W4256238377C20621625 @default.
- W4256238377 hasConceptScore W4256238377C25170562 @default.
- W4256238377 hasConceptScore W4256238377C2776572972 @default.
- W4256238377 hasConceptScore W4256238377C2778564446 @default.
- W4256238377 hasConceptScore W4256238377C2779825165 @default.
- W4256238377 hasConceptScore W4256238377C37263863 @default.
- W4256238377 hasConceptScore W4256238377C486523 @default.
- W4256238377 hasConceptScore W4256238377C62520636 @default.
- W4256238377 hasConceptScore W4256238377C71240020 @default.
- W4256238377 hasConceptScore W4256238377C7602139 @default.
- W4256238377 hasLocation W42562383771 @default.
- W4256238377 hasOpenAccess W4256238377 @default.
- W4256238377 hasPrimaryLocation W42562383771 @default.
- W4256238377 hasRelatedWork W2040079916 @default.
- W4256238377 hasRelatedWork W2056324960 @default.
- W4256238377 hasRelatedWork W2118956627 @default.
- W4256238377 hasRelatedWork W2752450517 @default.
- W4256238377 hasRelatedWork W2753616560 @default.
- W4256238377 hasRelatedWork W2951904070 @default.
- W4256238377 hasRelatedWork W3004925664 @default.
- W4256238377 hasRelatedWork W3187919423 @default.
- W4256238377 hasRelatedWork W4256238377 @default.
- W4256238377 hasRelatedWork W4312900175 @default.
- W4256238377 isParatext "false" @default.
- W4256238377 isRetracted "false" @default.
- W4256238377 workType "article" @default.