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- W4256241554 abstract "Various cationic initiators of the benzylammonium SbF6 type were synthesized from substituted benzyl chlorides and pyridine or N,N-dimethylaniline followed by exchange of the counter anion with SbF6. These benzylammonium SbF6 salts acted as latent thermal initiators in the cationic polymerization of glycidyl phenyl ether. A cationic curing system, consisting of an initiator, a polymer containing oxirane moiety and 3,4-epoxy cyclohexylmethyl 3,4-epoxy cyclohexyl carboxylate, was examined as a film forming mechanism. Furthermore, properties of the coating solutions and those films were evaluated. It was found that α,α-dimethylbenzyl pyridinium SbF6 was a superior latent thermal catalyst for cationic curing and that 3,4-epoxy cyclohexylmethyl 3,4-epoxy cyclohexyl carboxylate was effective in high-solids coatings." @default.
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- W4256241554 date "1996-06-01" @default.
- W4256241554 modified "2023-10-14" @default.
- W4256241554 title "Thermal cationic curing with benzylammonium salts — 2" @default.
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- W4256241554 doi "https://doi.org/10.1016/0300-9440(95)00612-5" @default.
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