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- W4256274504 abstract "Abstract The treatment of benzylallene‐substituted internal alkynes with [RhCl(CO) 2 ] 2 effects a novel cycloisomerization by C(sp 2 )−H bond activation to produce hexahydrophenanthrene derivatives. The reaction likely proceeds through consecutive formation of a rhodabicyclo[4.3.0] intermediate, σ‐bond metathesis between the C(sp 2 )−H bond on the benzene ring and the C(sp 2 )−Rh III bond, and isomerization between three σ‐, π‐, and σ‐allylrhodium(III) species, which was proposed based on experiments with deuterated substrates." @default.
- W4256274504 created "2022-05-12" @default.
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- W4256274504 date "2016-07-28" @default.
- W4256274504 modified "2023-09-25" @default.
- W4256274504 title "Construction of Hexahydrophenanthrenes By Rhodium(I)-Catalyzed Cycloisomerization of Benzylallene-Substituted Internal Alkynes through C−H Activation" @default.
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- W4256274504 doi "https://doi.org/10.1002/ange.201605640" @default.
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